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(BICYCLO[2.2.1]HEPTA-2,5-DIENE)CHLORORHODIUM(I) DIMER CAS:12257-42-0

(BICYCLO[2.2.1]HEPTA-2,5-DIENE)CHLORORHODIUM(I) DIMER is a dimeric compound containing rhodium(I) centers coordinated with bicyclo[2.2.1]hepta-2,5-diene ligands and chloride ions. Its chemical formula is RhCl(bicyclo[2.2.1]hepta-2,5-diene)₂. This dimeric complex exhibits unique structural and electronic properties, contributing to its significance in organometallic chemistry and catalysis.


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Application and Effect:

(BICYCLO[2.2.1]HEPTA-2,5-DIENE)CHLORORHODIUM(I) DIMER is applied in various catalytic reactions, leveraging its reactivity and coordination properties. One significant use is as a catalyst in cycloaddition reactions, such as cyclopropanation and cycloisomerization. These transformations enable the synthesis of cyclic compounds with high regio- and stereoselectivity, important in the preparation of pharmaceuticals, natural products, and fine chemicals. Moreover, the dimeric complex serves as a catalyst in carbonylation reactions, facilitating the addition of carbon monoxide to unsaturated substrates to form carbonyl compounds. Carbonylation processes are integral in industrial chemistry for the synthesis of acyl derivatives, esters, and carboxylic acids, highlighting the utility of (BICYCLO[2.2.1]HEPTA-2,5-DIENE)CHLORORHODIUM(I) DIMER in catalytic transformations. Furthermore, this compound finds application in the activation of small molecules for catalytic purposes, including hydrogenation and hydrosilylation reactions. Its ability to activate substrates such as hydrogen and silicon-based compounds contributes to the development of efficient and selective catalytic processes for the synthesis of functionalized molecules and intermediates. Additionally, (BICYCLO[2.2.1]HEPTA-2,5-DIENE)CHLORORHODIUM(I) DIMER is utilized in the catalytic functionalization of C-H bonds, enabling the direct transformation of inert C-H bonds into valuable functional groups. This catalytic strategy offers a streamlined approach to organic synthesis, avoiding prefunctionalization steps and reducing waste generation. Moreover, the dimeric complex serves as a precursor in the synthesis of other rhodium complexes and organometallic species, providing access to a diverse array of catalytic systems with tunable properties. These complexes find applications in various catalytic transformations, including cross-coupling reactions, hydrogenation, and carbon-carbon bond formation. In conclusion, (BICYCLO[2.2.1]HEPTA-2,5-DIENE)CHLORORHODIUM(I) DIMER demonstrates versatile applications in catalysis, encompassing cycloaddition reactions, carbonylation, small molecule activation, C-H functionalization, and the synthesis of other organometallic complexes. Its structural diversity and catalytic activity make it a valuable component in the toolkit of synthetic chemists seeking efficient and selective routes to complex molecules.

Product Sample:

Amino acid powder1
Amino acid powder2

Product Packing:

Amino acid powder3
Amino acid powder4
Amino acid powder5
Amino acid powder6

Additional Information:

Composition C14H16Cl2Rh28
Assay 99%
Appearance white powder
CAS No.  12257-42-0
Packing Small and bulk
Shelf Life 2 years
Storage Store in cool and dry area
Certification ISO.

 


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