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Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate CAS:99326-34-8

Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate is a complex compound containing a rhodium(I) center coordinated with two 1,5-cyclooctadiene ligands and trifluoromethanesulfonate counterions. Its chemical formula is Rh(COD)₂OTf. This compound serves as a versatile precursor in various catalytic reactions due to its stability and compatibility with a wide range of substrates.


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Application and Effect:

Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate finds diverse applications in catalysis, playing a crucial role in organic synthesis and catalytic transformations. One primary use is as a catalyst in the hydrosilylation reaction, where it facilitates the addition of silicon-based compounds to unsaturated substrates. This reaction is valuable in the synthesis of functionalized organosilanes, widely employed in the manufacture of silicones, pharmaceuticals, and fine chemicals. Furthermore, this compound serves as a catalyst in hydroformylation reactions, enabling the conversion of olefins into aldehydes through the addition of carbon monoxide and hydrogen. Hydroformylation reactions are essential in the production of industrial chemicals, including plasticizers, detergents, and alcohols, making Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate a key component in catalytic processes. Moreover, the complex is utilized in various carbon-carbon bond forming reactions, such as carbonylation and alkylation reactions. These transformations enable the synthesis of complex organic molecules with diverse structural motifs, including pharmaceuticals, agrochemicals, and natural products. The catalytic activity of the rhodium complex promotes high efficiency and selectivity in these bond-forming processes. Additionally, Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate is employed in the catalytic hydrogenation of unsaturated compounds, including alkenes, alkynes, and aromatic rings. This hydrogenation reaction leads to the formation of saturated products, which are valuable intermediates in organic synthesis and industrial processes. Furthermore, the complex serves as a catalyst in various cycloaddition reactions, such as [2+2] and [4+2] cycloadditions, enabling the construction of cyclic compounds with high regio- and stereocontrol. These cycloaddition processes are fundamental in the synthesis of natural products, pharmaceuticals, and functional materials. In conclusion, Bis(1,5-cyclooctadiene)rhodium(I) trifluoromethanesulfonate exhibits versatile applications in catalysis, encompassing hydrosilylation, hydroformylation, carbon-carbon bond formation, hydrogenation, and cycloaddition reactions. Its compatibility with a wide range of substrates and its efficient catalytic performance make it a valuable tool for synthetic chemists in the development of efficient and sustainable chemical processes.

Product Sample:

L-Arginine1
L-Arginine2

Product Packing:

L-Arginin3

Additional Information:

Composition C17H24F3O3RhS
Assay 99%
Appearance white powder
CAS No.  99326-34-8
Packing Small and bulk
Shelf Life 2 years
Storage Store in cool and dry area
Certification ISO.

 


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