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Carbonyltris(triphenylphosphine)rhodium(I)hydride CAS:17185-29-4

Carbonyltris(triphenylphosphine)rhodium(I) hydride, also known as CTPRH or Wilkinson’s catalyst, is an organometallic compound with the formula RhCl(PPh3)3.  It contains a central Rh(I) ion bound to CO ligand, PPh3, and H atoms.  The molecule has tetrahedral geometry around the Rh center due to its coordination environment.


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Application and Effect:

This versatile reagent finds application in numerous areas such as:

Organic Synthesis - In synthetic chemistry, this compound acts as a precatalyst for several important reaction processes like alkene reduction, carboxylic acid reductions, etc., which are often employed during drug discovery projects.

Catalytic Asymmetric Reactions - Due to chiral induction provided by phosphines, CTPRH catalyzed asymmetric allylic substitutions have been successfully applied in many enantioselective total syntheses of natural products or drugs.

Hydroformylation Processes - It's also utilized extensively in industry because of the ability to convert olefins into valuable linear aldehydes with high selectivity under mild conditions.

Overall, due to its unique structural features and diverse reactivities, Carbonyltris(triphenylphosphine)rhodium(I) hydride continues to be an essential tool across organometallic chemistry and beyond.

Product Sample:

L-Arginine1
L-Arginine2

Product Packing:

L-Arginin3

Additional Information:

Composition 3C18H15P.CO.HRh
Assay 99%
Appearance White powder
CAS No.  17185-29-4
Packing Small and bulk
Shelf Life 2 years
Storage Store in cool and dry area
Certification ISO.

 


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