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Cyclopropylmagnesium bromide CAS:23719-80-4

Cyclopropylmagnesium bromide (C3H5MgBr) is an organometallic compound belonging to the Grignard reagent family. It consists of a cyclopropyl group bonded to a magnesium bromide unit. This reagent is notable for its unique ring structure, which imparts distinctive reactivity patterns in organic synthesis. Cyclopropylmagnesium bromide is primarily employed as a nucleophile, participating in various chemical reactions to form carbon-carbon bonds. Its applications are significant in synthetic chemistry, particularly in the preparation of complex organic molecules and pharmaceutical intermediates.


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Application and Effect:

Cyclopropylmagnesium bromide (C₃H₅MgBr) is an important member of the Grignard reagent family, characterized by its cyclopropyl group linked to a magnesium atom coordinated with a bromine atom. The unique three-membered ring structure of cyclopropyl contributes to its distinct reactivity profile, making it a valuable asset in organic synthesis. One of the primary roles of cyclopropylmagnesium bromide is as a nucleophile in chemical reactions. This reagent readily reacts with electrophilic centers, such as carbonyl compounds, to facilitate the formation of carbon-carbon bonds. When cyclopropylmagnesium bromide interacts with aldehydes or ketones, it leads to the generation of alcohols through nucleophilic addition. For example, when reacting with formaldehyde, it produces secondary alcohols that serve as crucial building blocks in the synthesis of more complex organic molecules. Additionally, cyclopropylmagnesium bromide can participate in other transformations, such as reactions with epoxides and α,β-unsaturated carbonyl compounds. Its ability to attack these substrates enables the construction of intricate molecular frameworks that are often found in natural products and pharmaceuticals. Moreover, the presence of the strained cyclopropyl ring can impart unique stereoelectronic effects, influencing reaction pathways and selectivity. Despite its utility, working with cyclopropylmagnesium bromide requires careful handling due to its high reactivity with moisture and air. It must be stored under anhydrous conditions to prevent hydrolysis, which can lead to the release of hydrocarbons and the formation of undesirable byproducts. In summary, cyclopropylmagnesium bromide is a versatile and reactive Grignard reagent that plays a significant role in organic synthesis. Its ability to form carbon-carbon bonds and react with various electrophiles makes it an essential tool for chemists aiming to create complex organic molecules. Understanding its properties and reactivity patterns can significantly enhance synthetic strategies and contribute to advancements in chemical research, particularly in fields like medicinal chemistry and materials science.

Product Sample:

L-Arginine1
L-Arginine2

Product Packing:

L-Arginin3

Additional Information:

Composition C3H5BrMg
Assay 99%
Appearance white powder
CAS No.  23719-80-4
Packing Small and bulk
Shelf Life 2 years
Storage Store in cool and dry area
Certification ISO.

 


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