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(Pentamethylcyclopentadienyl)iridium(III) chloride dimer CAS:12354-84-6

(Pentamethylcyclopentadienyl)iridium(III) chloride dimer is a dimeric compound featuring iridium(III) centers coordinated with pentamethylcyclopentadienyl ligands and chloride ions. Its chemical formula is Ir(C₅Me₅)Cl₂. This dimeric complex exhibits distinctive structural and electronic properties, rendering it significant in organometallic chemistry and catalysis.


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Application and Effect:

(Pentamethylcyclopentadienyl)iridium(III) chloride dimer finds extensive applications in catalysis, contributing to various organic transformations and synthetic methodologies. One primary use is as a catalyst in C-H activation reactions, enabling the functionalization of inert C-H bonds in organic molecules. This catalytic process offers a direct and efficient route to complex molecular structures, bypassing the need for prefunctionalization steps. Moreover, the complex serves as a catalyst in C-C bond formation reactions, such as cross-coupling and carbon-carbon bond activation processes. These transformations enable the synthesis of biaryl compounds, heterocycles, and polyaromatic architectures, crucial in medicinal chemistry, materials science, and organic synthesis. Furthermore, (Pentamethylcyclopentadienyl)iridium(III) chloride dimer is utilized in the catalytic hydrogenation of unsaturated compounds, including alkenes, alkynes, and aromatic rings. This hydrogenation reaction leads to the selective reduction of multiple bonds, providing access to saturated products with high efficiency and selectivity. Additionally, the complex serves as a catalyst in various cyclization reactions, promoting the formation of cyclic compounds with diverse ring sizes and substitution patterns. These cyclization processes are fundamental in the synthesis of natural products, pharmaceuticals, and advanced materials. Moreover, (Pentamethylcyclopentadienyl)iridium(III) chloride dimer plays a crucial role in the activation of small molecules for catalytic transformations, including carbon dioxide and nitrogen. Its ability to activate these substrates under mild conditions enables their conversion into valuable products, contributing to the development of sustainable chemical processes. In conclusion, (Pentamethylcyclopentadienyl)iridium(III) chloride dimer exhibits versatile applications in catalysis, including C-H activation, C-C bond formation, hydrogenation, cyclization, and small molecule activation. Its efficiency, selectivity, and compatibility with a wide range of substrates make it a valuable catalyst in the advancement of synthetic methodologies and the synthesis of complex organic molecules.

Product Sample:

Amino acid powder1
Amino acid powder2

Product Packing:

Amino acid powder3
Amino acid powder4
Amino acid powder5
Amino acid powder6

Additional Information:

Composition Ir(CMe)Cl₂
Assay 99%
Appearance white powder
CAS No.  12354-84-6
Packing Small and bulk
Shelf Life 2 years
Storage Store in cool and dry area
Certification ISO.

 


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